In this paper, for both the steady and the unsteady stratifications, a set of analytical solutions of secondary Pollutant is obtained under the joint effects of transport, diffusion and chemical conversion and decay in the atmospheric boundary layer.The concentration distribution of the primary pollutant is improved, too. As a result of chemical conversion and decay,the primary pollutant decreases with the downwind distance more rapidly,especially as the mesoscale distance further than 10 km.Appropriately,a higher concentration of the secondary pollutant is stably held for a longer downwind distance.